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Bajpai, Anil Kumar, Shukla, Seeta. (1393). Designing of Plaster of Paris (PP) Containing Poly (vinyl alcohol) -g-Poly (2-Hydroxyethyl methacrylate-co-acrylic acid)(PVA-g-PHEMA-co-AA) Nanocomposites: Preparation, Characterization and Study of Physicochemical Behavior. هنرهای کاربردی, 2.(1), -. doi: 10.22075/ancr.2015.230
Anil Kumar Bajpai; Seeta Shukla. "Designing of Plaster of Paris (PP) Containing Poly (vinyl alcohol) -g-Poly (2-Hydroxyethyl methacrylate-co-acrylic acid)(PVA-g-PHEMA-co-AA) Nanocomposites: Preparation, Characterization and Study of Physicochemical Behavior". هنرهای کاربردی, 2., 1, 1393, -. doi: 10.22075/ancr.2015.230
Bajpai, Anil Kumar, Shukla, Seeta. (1393). 'Designing of Plaster of Paris (PP) Containing Poly (vinyl alcohol) -g-Poly (2-Hydroxyethyl methacrylate-co-acrylic acid)(PVA-g-PHEMA-co-AA) Nanocomposites: Preparation, Characterization and Study of Physicochemical Behavior', هنرهای کاربردی, 2.(1), pp. -. doi: 10.22075/ancr.2015.230
Bajpai, Anil Kumar, Shukla, Seeta. Designing of Plaster of Paris (PP) Containing Poly (vinyl alcohol) -g-Poly (2-Hydroxyethyl methacrylate-co-acrylic acid)(PVA-g-PHEMA-co-AA) Nanocomposites: Preparation, Characterization and Study of Physicochemical Behavior. هنرهای کاربردی, 1393; 2.(1): -. doi: 10.22075/ancr.2015.230

Designing of Plaster of Paris (PP) Containing Poly (vinyl alcohol) -g-Poly (2-Hydroxyethyl methacrylate-co-acrylic acid)(PVA-g-PHEMA-co-AA) Nanocomposites: Preparation, Characterization and Study of Physicochemical Behavior

Innovations in Materials: Current & Future
مقاله 9، دوره 2.، شماره 1، فروردین 2015    اصل مقاله (2.08 M)
نوع مقاله: Original Paper
شناسه دیجیتال (DOI): 10.22075/ancr.2015.230
نویسندگان
Anil Kumar Bajpai* 1؛ Seeta Shukla2
1Govt. Model Science College, South Civil LIne, Jabalpur, MP, India
2Dept of Chemistry Govt. Autonomous Science College Jabalpur MP India
تاریخ دریافت: 08 آبان 1393،  تاریخ بازنگری: 21 اسفند 1403،  تاریخ پذیرش: 26 بهمن 1393 
چکیده
In the present work plaster of paris containing polymer-based nanocomposites were prepared through chemical crosslinking and graft copolymerization of 2-hydroxyethyl methacrylate (HEMA) and acrylic acid (AA) on to polyvinyl alcohol (PVA) in the presence of ethylene glycol dimethacrylate (EGDMA) as crosslinker and potassium persulphate (KPS) and potassium metabisulphite (MBS) as redox components.  The structure of so prepared copolymers was confirmed by Fourier transform infrared (FTIR) spectroscopy while morphology was  examined using scanning electron microscopy (SEM) analysis.
The nanocomposites were found to show good mechanical properties as evident from the obtained experimental data. The maximum and minimum compressive strength of nanocomposites were found to be 29.5 (MPa) and 4.02 (MPa), respectively   whereas the maximum and minimum modulus were found to be 200 (MPa) and 34 (MPa). The water sorption behavior was found to be dependent on chemical composition of the nanocomposite matrix. The porosity of composite varied between 33 to 57%. The in vitroblood compatibility of the nanocomposite indicated that the adsorption of bovine serum albumin (BSA) varied from 0.015 to 0.047 mg g–1, the percentage haemolysis was between 12.3 to 23.7% and the weights of blood clot formed on the composite surfaces were found in the range 13 to 37 mg
کلیدواژه‌ها
Nanocomposites؛ Polymer؛ Mechanical properties؛ biocompatibility
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