Thermodynamic Study of Cement Paste under Sulfate Attack: A Review

[1] Santhanam, M., Cohen, M. D., Olek, J. (2001). “Sulfate attack research—whither now?.” Cement and concrete research, Vol. 3, no. 6, pp. 845-851.

[2] Mehta, P. K. (1973). “Mechanism of expansion associated with ettringite formation.” Cement and concrete research, Vol. 3, no. 1, pp. 1-6.

[3] Lafuma, H. (1929). “Theory of the expansion of cement.” Rev. Mater. Conc. Trave, Vol. 243, pp. 441-444.

[4] Taylor, H. F. W. (1994). “Sulfate reactions in concrete--microstructural and chemical aspects.” Ceramic Transactions, Vol. 40, pp. 61.

[5] Scherer, G. W. (1999). “Crystallization in pores.” Cement and Concrete research, Vol. 29, no. 8, pp. 1347-1358.

[6] Scherer, G. W. (2004). “Stress from crystallization of salt.” Cement and concrete research, Vol. 34, no. 9, pp. 1613-1624.

[7] Hime, W. G., Mather, B. (1999). “Sulfate attack,” or is it?.” Cement and Concrete Research, Vol. 29, no. 5, pp. 789-791.

[8] Tavakoli, D., Tarighat, A., Beheshtian, J. (2019). “Nanoscale investigation of the influence of water on the elastic properties of C–S–H gel by molecular simulation.” Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications, Vol. 233, no.7, pp. 1295-1306.

[9] Tavakoli, D., Gao, P., Tarighat, A., Ye, G. (2019). “Multi-scale Approach from Atomistic to Macro for Simulation of the Elastic Properties of Cement Paste.” Iranian Journal of Science and Technology, Transactions of Civil Engineering, pp. 1-13.

[10] Tarighat, A., Tavakoli, D. (2019). “Estimation of the elastic properties of important calcium silicate hydrates in nano scale-a molecular dynamics approach.” Journal of Rehabilitation in Civil Engineering, Vol. 7, no. 4, pp. 18-36.

[11] Akbarzadeh Bengar, H., Yavari, M. R. (2016). “Simulation of the Reactive Powder Concrete (RPC) Behavior Reinforcing with Resistant Fiber Subjected to Blast Load.” Journal of Rehabilitation in Civil Engineering, Vol. 4, no. 1, pp. 63-77.

[12] Tavakoli, D., Dehkordi, R. S., Divandari, H., de Brito, J. (2020). “Properties of roller-compacted concrete pavement containing waste aggregates and nano SiO2.” Construction and Building Materials, Vol. 249, pp. 118747.

[13] SadrMomtazi, A., Kohani Khoshkbijari, R. (2017). “An investigation on in-situ strength and bonding strength of Polymer Modified Concretes (PMC) as repair overlays on conventional concrete substrate.” Journal of Rehabilitation in Civil Engineering, Vol. 5, no. 1, pp. 67-78.

[14] SadrMomtazi, A., Kohani Khoshkbijari, R. (2017). “An investigation on in-situ strength and bonding strength of Polymer Modified Concretes (PMC) as repair overlays on conventional concrete substrate.” Journal of Rehabilitation in Civil Engineering, Vol. 5, no. 1, pp. 67-78.

[15] Qodousian, O., Sadrmomtazi, A. (2019). “Study of effect of paste volume, water to cementitious materials and fiber dosages on rheological properties and in-situ strength of self-compacting concrete.” Journal of Rehabilitation in Civil Engineerin, Vol. 7, no. 2, pp. 218-228.

[16] Hemmati, A., Kheyroddin, A., Farzad, M. (2020). “Experimental Study of Reinforced Concrete Frame Rehabilitated by Concentric and Eccentric Bracing.” Journal of Rehabilitation in Civil Engineering, Vol. 8, no. 1, pp. 97-108.

[17] Fallahtabar, M., Tavakoli, H. (2018). “Estimation of mechanical and durability properties of self-compacting concrete with fibers using ultrasonic pulse velocity.” Journal of Rehabilitation in Civil Engineerin, Vol. 6, no. 2, pp. 43-53.

[18] Clifton, J. R., Frohnsdorff, G. J., Ferraris, C. F. (1999, December). “Standards for evaluating the susceptibility of cement-based materials to external sulfate attack.” In Materials Science of Concrete.

[19] Cohen, M. D., Mather, B. (1991). “Sulfate attack on concrete: research needs.” Materials Journal, Vol. 88, no. 1, pp. 62-69.

[20] Skalny, J., Pierce, J. (1999). “Sulfate attack issues.” Material Science of Concrete—Sulfate Attack Mechanisms, American Ceramic Society, Westerville, OH, pp. 49-64.

[21] Drimalas, T., Clement, J. C., Folliard, K. J., Dhole, R., Thomas, M. D. (2011). “Laboratory and field evaluations of external sulfate attack in concrete.” (No. FHWA/TX-11/0-4889-1).

[22] Collepardi, M. (2003). “A state-of-the-art review on delayed ettringite attack on concrete.” Cement and concrete Composites, Vol. 25, no. 4-5, pp. 401-407.

[23] Czerewko, M.A. Cripps, J.C. Duffell, C.G. and Reid, J.M. (2002). “The distribution and evaluation of sulfur species in geological materials and manmade fills.” Proceedings of 1st International Conference on Thaumasite, BRE, London.

[24] Clark, L. (1999). “The thaumasite form of sulfate attack: Risks, diagnosis, remedial works and guidance on new construction.” Report of the Thaumasite Expert Group. Department of the Environment, Transport and the Regions.

[25] White, S. J., Smy, R. H., Lynch, M. (2002, June). “UK Highways Agency Area 2: managing the threat of thaumasite sulfate attack.” In Proceedings of the First International Conference on Thaumasite in Cementitious Materials.

[26] Mehta, P. K. (1983). “Mechanism of sulfate attack on portland cement concrete—Another look.” Cement and Concrete Research, Vol. 13, no. 3, pp. 401-406.

[27] Longworth, T. I. (2003). “Contribution of construction activity to aggressive ground conditions causing the thaumasite form of sulfate attack to concrete in pyritic ground.” Cement and Concrete Composites, Vol. 25, no. 8, pp. 1005-1013.

[28] Crammond, N. J. (2003). “The thaumasite form of sulfate attack in the UK.” Cement and Concrete Composites, Vol. 25, no. 8, pp. 809-818.

[29] Skalny, J., Marchand, J., Odler, I. “Sulfate attack on concrete.” 2002.

[30] Tian, B., Cohen, M. D. (2000). “Does gypsum formation during sulfate attack on concrete lead to expansion?.” Cement and concrete research, Vol. 30, no. 1, pp. 117-123.

[31] Müllauer, W., Beddoe, R. E., Hilbig, H., Heinz, D. (2012). “Mechanisms of sulfate attack for plain and fly ash cements at different storage temperatures and sulfate concentrations.” In ICDC 2012, International Congress on Durability of Concrete.

[32] Santhanam, M., Cohen, M. D., Olek, J. (2003). “Effects of gypsum formation on the performance of cement mortars during external sulfate attack.” Cement and concrete research, Vol. 33, no. 3, pp. 325-332.

[33] Skalny, J., Marchand, J., Odler, I. (2002). “Sulfate Attack on Concrete.” E&FN Spon. London, New York, Sections, Vol. 4, pp. 5.

[34] Hewlett, PC. (editor). (1998). “Lea’s chemistry of cement and concrete.” Arnold, UK.

[35] Bensted, J. (2007). “Thaumasite – part 2: origins, ramifications and discussions related to the thaumasite
expert group report.” Cement-Lime-Concrete, XII/LXXIV(5): pp. 245–260.

[36] Mehta, P. K., Pirtz, D., Polivka, M. (1979). “Properties of alite cements.” Cement and concrete research, Vol. 9, no. 4, pp. 439-450.

[37] Małolepszy, J. Rodek, Mróz. (2006, March-April). “Conditions of thaumasite formation.” Cement-LimeConcrete, XI/LXXIII, pp. 93–101.

[38] Révay, M., Gável, V. (2003). “Thaumasite sulphate attack at the concrete structures of the Ferenc Puskás stadium in Budapest.” Cement and Concrete Composites, Vol. 25, no. 8, pp. 1151-1155.

[39] Clark, L. A. (2000). “Thaumasite Expert Group one-year review.” London, Department of the Environment, Transport and the Regions.

[40] Balonis, M. (2010). “The Influence of Inorganic Chemical Accelerators and Corrosion Inhibitors on the Mineralogy of Hydrated Portland Cement Systems.” (Doctoral dissertation, Aberdeen University).

[41] Schmidt, T. (2007). “Sulfate attack and the role of internal carbonate on the formation of thaumasite.” (No. THESIS). EPFL.

[42] Zhang, Z., Wang, Q., Chen, H., Zhou, Y. (2017). “Influence of the initial moist curing time on the sulfate attack resistance of concretes with different binders.” Construction and Building Materials, Vol. 144, pp. 541-551.

[43] Müllauer, W., Beddoe, R. E., Heinz, D. (2013). “Sulfate attack expansion mechanisms.” Cement and concrete research, Vol. 52, pp. 208-215.

[44] The EUROMIN project: http://euromin.w3sites.net/mineraux/THAUMASITE. html, February 2007.

[45] Stark, D. C. (2003). “Occurrence of thaumasite in deteriorated concrete.” Cement and Concrete Composites, Vol. 25, no. 8, pp. 1119-1121.

[46] Sims, I., Huntley, S. A. (2004). “The thaumasite form of sulfate attack-breaking the rules.” Cement and concrete composites, Vol. 26, no. 7, pp. 837-844.

[47] Crammond, N.J. (2003). “Thaumasite in failed cement mortars and renders.” Cement & Concrete Research Vol. 15, pp. 1039-1050.

[48] Moore, A.E. Taylor, H.F.W. (1970). “Crystal structure of thaumasite.” Acta Crystallographica, Section B Vol. 26, pp. 386-393.

[49] Edge, R. A., Taylor, H. F. W. (1971). “Crystal structure of thaumasite,[Ca3Si (OH) 6.12 H2O](SO4)(CO3) .” Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry, Vol. 27, no. 3, pp. 594-601.

[50] Edge, R. A., Taylor, H. F. W. (1969). “Crystal structure of thaumasite, a mineral containing [Si (OH) 6] 2− groups.” Nature, Vol. 224, no. 5217, pp. 363-364.

[51] Nielsen, P., Nicolai, S., Darimont, A., Kestemont, X. (2014). “Influence of cement and aggregate type on thaumasite formation in concrete.” Cement and Concrete Composites, Vol. 53, pp. 115-126.

[52] Słomka-Słupik, B. (2009). “The changes of phases composition of the paste from cement CEM III/A under the influence of NH4Cl water solution.” Cement Wapno Beton, Vol. 2, pp. 61-66.

[53] Diamond, S., Lee, R. J. (1999). “Microstructural alterations associated with sulfate attack in permeable concretes.” American Ceramic Society, Inc, Materials Science of Concrete: Sulfate Attack Mechanisms(USA), pp. 123-173.

[54] Bensted, J. (2003). “Thaumasite––direct, woodfordite and other possible formation routes.” Cement and Concrete Composites, Vol. 25, no. 8, pp. 873-877.

[55] Słomka-Słupik, B., Zybura, A. (2017). “Thaumasite non-sulphate attack at ambient temperature and pressure.” Architecture Civil Engineering Environment, Vol.10, no. 3, pp. 73-80.

[56] Maingyu, H. Fumei, L. Mingshu, T. (2006). “The thaumasite form of sulfate attack in concrete of Yongan Dam.” Cement and Concrete Research. Vol. 36, no. 10, pp. 2006–2008.

[57] Hobbs, D. W. (2003). “Thaumasite sulfate attack in field and laboratory concretes: implications for specifications.” Cement and Concrete Composites, Vol. 25, no. 8, pp. 1195-1202.

[58] Czerewko, M. A., Cripps, J. C., Reid, J. M., & Duffell, C. G. (2003). “Sulfur species in geological materials––sources and quantification.” Cement and Concrete Composites, Vol. 25, no. 7, pp. 657-671.

[59] Erlin, B. Stark, DC. (1965). “Identification and occurrence of thaumasite in concrete.” Highway Res Record Vol. 113, pp. 108–13.

[60] Rahman, M. M., Bassuoni, M. T. (2014). “Thaumasite sulfate attack on concrete: Mechanisms, influential factors and mitigation.” Construction and Building Materials, Vol. 73, pp. 652-662.

[61] Wimpenny, D., Slater, D. (2003). “Evidence from the highways agency thaumasite investigation in Gloucestershire to support or contradict postulated mechanisms of thaumasite formation (TF) and thaumasite sulfate attack (TSA) .” Cement and Concrete Composites, Vol. 25, no. 8, pp. 879-888.

[62] Pagano, M., Daligand, D., Bernhard, J. D., Levandowsky, L. (1976). “Study of the adhesion of faience tiles on projection plaster.” L'Industrie Ceram, Vol. 699, no. 10, pp. 685-690.

[63] Crammond, N. J., Nixon, P. J. (1993, October). “Deterioration of concrete foundation piles as a result of thaumasite formation.” In Proceedings of the 6th International Conference on Durability of Building Materials and Components (Vol. 1, pp. 295-305). E. and FN Spon London.

[64] Crammond, N. (2002). “The occurrence of thaumasite in modern construction–a review.” Cement and Concrete Composites, Vol. 24, no. 3-4, pp. 393-402.

[65] Brown, P. W., Doerr, A. (2000). “Chemical changes in concrete due to the ingress of aggressive species.” Cement and concrete research, Vol. 30, no. 3, pp. 411-418.

[66] Novak, G. A., Colville, A. A. (1989). “Efflorescent mineral assemblages associated with cracked and degraded residential concrete foundations in Southern California.” Cement and Concrete Research, Vol. 19, no. 1, pp. 1-6.

[67] Deloye, F. X., Louarn, N., Loos, G. (1988). “Examples of masonry analysis. The case of the Puberg Tunnel.” Bulletin de Liaison des Laboratoires des Ponts et Chaussées, Vol. 163, no. 1, pp. 17-24.

[68] Collepardi, M., Collepardi, S., Troli, R. (2007, June). “Pratical applications of SCC in european works.” In Proc int conf: sustainable construction materials and technologies, special papers proceedings. Pub. UW Milwaukee CBU (pp. 51-50).

[69] Baronio, G., Berra, M. (1984). “Concrete deterioration with the formation of thaumasite–analysis of the causes.” Il Cemento, Vol. 83, no. 3, pp. 169-184.

[70] Crammond, NJ. Dunster, AD. (1997). “Avoiding the deterioration of cement-based building materials; Lessons from case studies 1.” BRE Lab. Report BR 324. UK: Construction Research Communications Ltd (CRC).

[71] Bickley, J. A., Hemmings, R. T., Hooton, R. D., Balinski, J. (1994). “Thaumasite related deterioration of concrete structures.” Special Publication, Vol. 144, pp. 159-176.

[72] Snedker, E. A. (1996). “M40-lime stabilisation experiences.” In Lime Stabilisation: Proceedings of the seminar held at Loughborough University Civil & Building Engineering Department on 25 September 1996 (pp. 142-158). Thomas Telford Publishing.

[73] Freyburg, E., Berninger, A. M. (2003). “Field experiences in concrete deterioration by thaumasite formation: possibilities and problems in thaumasite analysis.” Cement and Concrete Composites, Vol. 25, no. 8, pp. 1105-1110.

[74] Schmidt, T., Lothenbach, B., Romer, M., Scrivener, K., Rentsch, D., Figi, R. (2008). “A thermodynamic and experimental study of the conditions of thaumasite formation.” Cement and Concrete Research, 38(3), 337-349.

[75] Modarres, Yaghout. (2016). “Thermodynamical Simulation of sulfate attack on hardened cement paste.” Thesis for degree of M.Sc in Structural Engineering under supervision of Dr. Amir Tarighat. Shahid Rajaee Teacher Training University, Faculty of Civil Engineering, Iran, Tehran. (in persian).

[76] Monteiro, P. J., Kurtis, K. E. (2003). “Time to failure for concrete exposed to severe sulfate attack.” Cement and Concrete research, Vol. 33, no. 7, pp. 987-993.

[77] Brueckner, Rene. (2007). “Accelerating the thaumasite form of sulfate attack and an investigation of its effects on skin fricyion.” Phd Thesis, School of Civil Engineering University of Birmingham.

[78] Lachaud, R. (1979). “Thaumasite and ettringite in building materials.” ANN. INST. TECH. BATIM. TRAV. PUBLICS Ann. Inst. Tech. Batim. Trav. Publics, (370), 167.

[79] Bensted, J. (1988). “Thaumasite a deterioration product of hardened cement structures.” Il Cemento, Vol. 85, no. 1, pp. 3-10.

[80] Crammond, N. J., Halliwell, M. A. (1995). “The thaumasite form of sulfate attack in concretes containing a source of carbonate ions--a microstructural overview.” Special Publication, Vol. 154, pp. 357-380.

[81] Collett, G., Crammond, N. J., Swamy, R. N., Sharp, J. H. (2004). “The role of carbon dioxide in the formation of thaumasite.” Cement and Concrete Research, Vol. 34, no. 9, pp. 1599-1612.

[82] Köhler, S., Heinz, D., Urbonas, L. (2006). “Effect of ettringite on thaumasite formation.” Cement and Concrete Research, Vol. 36, no. 4, pp. 697-706.

[83] Irbe, L., Beddoe, R. E., Heinz, D. (2019). “The role of aluminium in CASH during sulfate attack on concrete.” Cement and Concrete Research, Vol. 116, pp. 71-80.

[84] Mangat, P. S., El-Khatib, J. M. (1992). “Influence of initial curing on sulphate resistance of blended cement concrete.” Cement and Concrete Research, Vol. 22, no. 6, pp. 1089-1100.

[85] Lee, S. T., Moon, H. Y., Swamy, R. N. (2005). “Sulfate attack and role of silica fume in resisting strength loss.” Cement and Concrete Composites, Vol. 27, no. 1, pp. 65-76.

[86] Chindaprasirt, P., Kanchanda, P., Sathonsaowaphak, A., Cao, H. T. (2007). “Sulfate resistance of blended cements containing fly ash and rice husk ash.” Construction and Building Materials, Vol. 21, no. 6, pp. 1356-1361.

[87] Giaccio, G., de Sensale, G. R., Zerbino, R. (2007). “Failure mechanism of normal and high-strength concrete with rice-husk ash.” Cement and concrete composites, Vol. 29, no. 7, pp. 566-574.

[88] Chatveera, B., Lertwattanaruk, P. (2009). “Evaluation of sulfate resistance of cement mortars containing black rice husk ash.” Journal of environmental management, Vol. 90, no. 3, pp. 1435-1441.

[89] Ramezanianpour, Ali akbar. Mansour, Peydayesh. Mohammad reza, Shah nazari. Shapour, Tahouni. Parviz, ghodousi. Esmael, Ganjian. (2010). “Concrete technology (materials, properties, technology).” Iran, Tehran, University Press Department of Amir Kabir University (in persian).

[90] Tosun-Felekoğlu, K. (2012). “The effect of C3A content on sulfate durability of Portland limestone cement mortars.” Construction and Building Materials, Vol. 36, pp. 437-447.

[91] Chu, H. Y., Chen, J. K. (2013). “Evolution of viscosity of concrete under sulfate attack.” Construction and Building Materials, Vol. 39, pp. k46-50.

[92] Zhu, J., Cao, Y. H., Chen, J. Y. (2013). “Study on the evolution of dynamic mechanics properties of cement mortar under sulfate attack.” Construction and Building Materials, Vol. 43, pp. 286-292.

[93] Kunther, Wolfgang. Barbara, Lothenbach. Karen L, Scrivener. (2013). “Deterioration of mortar bars immersed in magnesium containing sulfate solutions.” Laboratory of Construction Materials, EPFL, Lausanne, Switzerland.

[94] Kunther, W., Lothenbach, B., Scrivener, K. L. (2013). “On the relevance of volume increase for the length changes of mortar bars in sulfate solutions.” Cement and Concrete Research, Vol. 46, pp. 23-29.

[95] Ramezanianpour, Ali akbar. Pouya, Pourbeik. Faramarz, Moodi. (2013). “Sulphate Attack of Concretes Containing Rice Husk Ash.” Amirkabir Journal of Science & Research (Civil & Environmental Engineering). Vol. 45, no. 1, pp. 3-5. (in persian).

[96] Ramezanianpour, Ali akbar. S. S, Mirvalad. E, Aramoon. M, Peydaayesh. (2014). “Effect of Four Iranian Natural Pozzolans on Concrete Durability Against Sulfate Attack.” Amirkabir Journal of Science & Research (Civil & Environmental Engineering). Vol. 46, no. 2, pp. 5-7. (in persian).

[97] Farokhzad, Reza. Sajad, Yaseri. Mohammad Hosein, Entezarian. Amir, Yavari. (2016). “Investigating Effects of Sulfates on Compressive Strength of Different Types of Pozzolan Concrete and Measuring Penetration Rate by Ultrasound Tests at Different Ages.” Concrete research quartery journal, university of Guilan. Vol. 9, no. 1-15, pp. 113-130. (in persian).

[98] Mwiti, M. J., Thiong'o, J. K., Muthengia, W. J. (2018). “Properties of activated blended cement containing high content of calcined clay.” Heliyon, Vol. 4, no. 8, e00742.

[99] Akasha, A. M., Abdullah, J. M. (2018). “Sulfate Resistance of Cement Mortar Containing Metakaolin.” In Calcined Clays for Sustainable Concrete (pp. 8-14). Springer, Dordrecht.

[100] Yu, C., Yuan, P., Yu, X., Liu, J. (2018). “Degradation of Calcined Clay-Limestone Cementitious Composites Under Sulfate Attack.” In Calcined Clays for Sustainable Concrete (pp. 110-116). Springer, Dordrecht.

[101] Shi, Z., Ferreiro, S., Lothenbach, B., Geiker, M. R., Kunther, W., Kaufmann, J., ... & Skibsted, J. (2019). “Sulfate resistance of calcined clay–Limestone–Portland cements.” Cement and Concrete Research, Vol. 116, pp. 238-251.

[102] Liu, P., Chen, Y., Yu, Z., Chen, L., Zheng, Y. (2020). “Research on Sulfate Attack Mechanism of Cement Concrete Based on Chemical Thermodynamics.” Advances in Materials Science and Engineering, 2020.

[103] Grovea, D. B., Wood, W. W. (1979). “Prediction and field verification of subsurface‐water quality changes during artificial recharge.” Lubbock, Texas. Groundwater, Vol. 17, no. 3, pp. 250-257.

[104] Atkinson, A., Haxby, A., Hearne, J. A. (1988). “The chemistry and expansion of limestone-Portland cement mortars exposed to sulphate containing solutions.” (No. NSS/R--127). United Kingdom Nirex.

[105] Saetta, A. V., Schrefler, B. A., Vitaliani, R. V. (1993). “The carbonation of concrete and the mechanism of moisture, heat and carbon dioxide flow through porous materials.” Cement and Concrete Research, Vol. 23, no. 4, pp. 761-772.

[106] J. M, Pommersheim. Clifton, J.R. (1994). “Expansion of cementitious materials exposed to sulfate solutions.” Mat. Res. Soc. Symp. Proc. 333:363-368.

[107] Casanova, I., Aguado, A., Agulló, L. (1997). “Aggregate expansivity due to sulfide oxidation—II. Physico-chemical modeling of sulfate attack.” Cement and concrete research, Vol. 27, no. 11, pp. 1627-1632.

[108] Truc, O., Ollivier, J. P., Nilsson, L. O. (2000). “Numerical simulation of multi-species diffusion.” Materials and Structures, Vol. 33, no. 9, pp. 566-573.

[109] Rothstein, D., Thomas, J. J., Christensen, B. J., Jennings, H. M. (2002). “Solubility behavior of Ca-, S-, Al-, and Si-bearing solid phases in Portland cement pore solutions as a function of hydration time.” Cement and Concrete Research, Vol. 32, no. 10, pp. 1663-1671.

[110] Shazali, M. A., Baluch, M. H., Al-Gadhib, A. H. (2006). “Predicting residual strength in unsaturated concrete exposed to sulfate attack.” Journal of Materials in Civil Engineering, Vol. 18, no. 3, pp. 343-354.

[111] Samson, E., Marchand, J. (2007). “Modeling the transport of ions in unsaturated cement-based materials.” Computers & Structures, Vol. 85, no. 23-24, pp. 1740-1756.

[112] Lothenbach, B., Winnefeld, F. (2006). “Thermodynamic modelling of the hydration of Portland cement.” Cement and Concrete Research, Vol. 36, no. 2, pp. 209-226.

[113] Ma, B., Gao, X., Byars, E. A., Zhou, Q. (2006). “Thaumasite formation in a tunnel of Bapanxia Dam in Western China.” Cement and Concrete Research, Vol. 36, no. 4, pp. 716-722.

[114] Lothenbach, B. (2010). Thermodynamic equilibrium calculations in cementitious systems.” Materials and Structures, Vol. 43, no. 10, pp. 1413-1433.

[115] Lothenbach, B., Bary, B., Le Bescop, P., Schmidt, T., Leterrier, N. (2010). “Sulfate ingress in Portland cement.” Cement and Concrete Research, Vol. 40, no. 8, pp. 1211-1225.

[116] Lothenbach, B., Damidot, D., Matschei, T., Marchand, J. (2010). “Thermodynamic modelling: state of knowledge and challenges.” Advances in cement research, Vol. 22, no. 4, vol. 211-223.

[117] Damidot, D., Lothenbach, B., Herfort, D., Glasser, F. P. (2011). “Thermodynamics and cement science.” Cement and Concrete Research, Vol. 41, no. 7, pp. 679-695.

[118] Bary, B. (2008). “Simplified coupled chemo‐mechanical modeling of cement pastes behavior subjected to combined leaching and external sulfate attack.” International journal for numerical and analytical methods in geomechanics, Vol. 32, no. 14, pp. 1791-1816.

[119] Bary, B., Leterrier, N., Deville, E., Le Bescop, P. (2014). “Coupled chemo-transport-mechanical modelling and numerical simulation of external sulfate attack in mortar.” Cement and Concrete Composites, Vol. 49, pp. 70-83.

[120] Idiart, A. E., López, C. M., Carol, I. (2011). “Chemo-mechanical analysis of concrete cracking and degradation due to external sulfate attack: A meso-scale model.” Cement and Concrete Composites, Vol. 33, no. 3, pp. 411-423.

[121] Mobasher, B. (2006). “Modeling of stiffness degradation and expansion in cement based materials subjected to external sulfate attack.” Transport Properties and Concrete Qualyty. Materials Science of Concrete. The American Ceramic Society. John Willy & Sons. New Jersey-2007.-c, 157-171.

[122] Mobasher, B., Ferraris, C. (2004, March). “Simulation of expansion in cement based materials subjected to external sulfate attack.” In RILEM International Symposium Proceedings: Advances in Concrete through Science and Engineering.

[123] Zuo, X. B., Sun, W., Yu, C. (2012). “Numerical investigation on expansive volume strain in concrete subjected to sulfate attack.” Construction and Building Materials, Vol. 36, pp. 404-410.

[124] Gospodinov, P. N. (2005). “Numerical simulation of 3D sulfate ion diffusion and liquid push out of the material capillaries in cement composites.” Cement and Concrete Research, Vol. 35, no. 3, pp. 520-526.

[125] Schmidt, Thomas, Barbara Lothenbach, Michael Romer, Jürg Neuenschwander, Karen Scrivener. "Physical and microstructural aspects of sulfate attack on ordinary and limestone blended Portland cements." Cement and Concrete Research 39, no. 12 (2009), pp. 1111-1121.

[126] Kunther, W., Lothenbach, B. (2018). “Improved volume stability of mortar bars exposed to magnesium sulfate in the presence of bicarbonate ions.” Cement and Concrete Research, Vol. 109, pp. 217-229.

[127] Tarighat, Amir. Milad, Mohammadi. Yaghut, Modarres. (2016). “Thermodynamic modeling of cement containing slag hydration.” In Proceedings of the 2nd International Conference on Modern Research in Civil Engineering, Architecture, Urban Management and Environment. Tehran, Iran. (in persian).

[128] Tarighat, Amir. Milad, Mohammadi. Yaghut, Modarres. (2016). “Thermodynamic modeling of cement containing Silica Fume hydration.” In Proceedings of the 8th National Conference of Concrete. Tehran, Iran. (in persian).

[129] Tarighat, Amir. Yaghut, Modarres. (2016). “Investigation of the sulfate attack mechanism in cement containing Silica Fume using thermodynamic modeling.” In Proceedings of the 8th National Conference of Concrete. Tehran, Iran. (in persian).

[130] Tarighat, Amir. Yaghut, Modarres. Milad, Mohammadi. (2016). “Thermodynamic modeling of cement containing slag in sulfate environments.” In Proceedings of the 2nd International Conference on Modern Research in Civil Engineering, Architecture, Urban Management and Environment. Tehran, Iran. (in persian).

[131] Tarighat, Amir. Milad, Mohammadi. (2017). “Thermodynamic study of cement containing slag pore solution during hydration.” In Proceedings of the 9th National of Concrete. Tehran, Iran. (in persian).

[132] Tarighat, A., Modarres, Y., Mohammadi, M. (2018). “Thermodynamic modeling of the effects of wollastonite-silica fume combination in the cement hydration and sulfate attack.” Civil Engineering Infrastructures Journal, Vol. 51, no. 1, pp. 87-100.

[133] Tarighat, Amir. Yaghut, Modarres. And Milad, Mohammadi. (2018). “Thermodynamic simulation of sulfate attack in cement mortars.” Modares Civil Engineering Journal (M.C.E.J). Vol. 18, no. 2, pp. 159-168. (in persian).

[134] Tarighat, Amir. Yaghut, Modarres. (2018). “Thermodynamic modeling of sulfate attack on hardened cement paste containing slag and investigation of the effect of various sulfate solutions.” Journal of concrete structure and material, Iranian concrete society (ics). Vol. 2, no. 4, pp. 32-43. (in persian).

[135] Tarighat, Amir. Milad, Mohammadi. Yaghut, Modarres. (2018). “Thermodynamical Study of Hydration and Chemical Shrinkage of Cement Containing Slag.” Sharif Journal, civil engineering. Vol. 34, no. 4.2, pp. 75-82. (in persian).

[136] Cao, Y., Guo, L., Chen, B., Fei, X. (2020). “Modeling early age hydration kinetics and the hydrated phase of cement paste blended with chloride and sulfate.” Construction and Building Materials, 261, p.120537.

[137] Cao, Y., Guo, L., Chen, B., Wu, J. (2020). “Thermodynamic modelling and experimental investigation on chloride binding in cement exposed to chloride and chloride-sulfate solution.” Construction and Building Materials, 246, p. 118398.

[138] Li, C., Jiang, Z., Myers, R. J., Chen, Q., Wu, M., Li, J., Monteiro, P. J. (2020). “Understanding the sulfate attack of Portland cement–based materials exposed to applied electric fields: Mineralogical alteration and migration behavior of ionic species.” Cement and Concrete Composites, p. 103630.

[139] Wee, T. H., Suryavanshi, A. K., Wong, S. F., Rahman, A. A. (2000). “Sulfate resistance of concrete containing mineral admixtures.” Materials Journal, Vol. 97, no. 5, pp. 536-549.

[140] Soive, A., Tran, V. Q. (2017). “External sulfate attack of cementitious materials: New insights gained through numerical modeling including dissolution/precipitation kinetics and surface complexation.” Cement and Concrete Composites, Vol. 83, pp. 263-272.