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Growth and Characterization of 1, 2, 3- Benzotriazole 2-chloro 4-nitrobenzoic Acid (BCNB) Single Crystal for NLO Applications | ||
Progress in Physics of Applied Materials | ||
دوره 2، شماره 1 - شماره پیاپی 2، بهمن 2022، صفحه 21-25 اصل مقاله (1003.55 K) | ||
نوع مقاله: Original Article | ||
شناسه دیجیتال (DOI): 10.22075/ppam.2022.26678.1025 | ||
نویسندگان | ||
B. Sahaya Infant Lasalle* ؛ T. Kamalesh؛ P. Karuppasamy؛ M. Senthil Pandian؛ P. Ramasamy | ||
SSN Research Centre, Sri Sivasubramaniya Nadar College of Engineering, Chennai-603110, Tamil Nadu, India. | ||
تاریخ دریافت: 18 فروردین 1401، تاریخ بازنگری: 19 خرداد 1401، تاریخ پذیرش: 20 خرداد 1401 | ||
چکیده | ||
The organic single crystal of 1,2,3- benzotriazole 2-chloro 4-nitrobenzoic acid (BCNB) was successfully grown by slow evaporation solution method using methanol as a solvent. The single crystal X-ray diffraction was used to analyse the lattice cell parameters of the grown BCNB crystal. The cell and lattice parameters of the BCNB crystal confirms the formation of monoclinic crystal structure with the P21/n space group. The diffraction planes (h,k,l) were determined by the powder X-ray diffraction (PXRD), which is in good agreement with the corresponding CIF file. The BCNB crystal exhibits good optical transmittance in the entire visible region, which is evident from the UV-Visible-NIR analysis. The photoconductivity analysis exposes the negative photoconductive nature of BCNB crystal. The self-defocusing and reverse saturable absorption effects of the BCNB is evident from the Z-scan experiment, which is prescribed in closed and open apertures and these results were used to deduce the 3rd order NLO parameters like n2, β and (χ(3)). | ||
کلیدواژهها | ||
Nonlinear optics؛ Single crystal؛ PXRD؛ UV-Visible-NIR؛ Z-scan | ||
مراجع | ||
[1] A. Senthil, P. Ramasamy, Investigation on the SR method growth, etching, birefringence, laser damage threshold and thermal characterization of strontium bis (hydrogen L-malate) hexahydrate single crystal, J. Cryst. Growth. 401 (2014) 200-204. [2] B. Babu, J. Chandrasekaran, and S. Balaprabhakaran, Growth, structural, spectral, optical and electrical properties of 2-aminophenol single crystals, Optik. 125 (2014) 3005-3008. [3] N. Prabavathi, A. Nilufer, & V. Krishnakumar, FT-IR, FTRaman and DFT quantum chemical study on the molecular conformation, vibrational and electronic transitions of 1-(m-(trifluoromethyl) phenyl) piperazine. Spectrochim. Acta A Mol. Biomol. 121 (2014) 483-493. [4] P. Vijayakumar, G. A. Babu, & P. Ramasamy, Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluenesulphonate. Materials Research Bulletin, 47 (2012) 957-962. [5] A. Thirunavukkarsu, S. Sudhahar, G. Maheshwaran, T. Sujatha, P. R. Umarani & R. M. Kumar, Synthesis, growth, structural, optical, thermal and mechanical properties of bis-benzotriazole trichloroacetic acid single crystals. Bull. Mater. Sci. 43 (2020) 1-11. [6] C. B. Aakeröy, A. M. Beatty, B. A. Helfrich, & M. Nieuwenhuyzen, Do polymorphic compounds make good cocrystallizing agents? A structural case study that demonstrates the importance of synthon flexibility. Crystal growth & design, 3 (2003) 159-165. [7] K. S. Ramesh, M. Saravanabhavan, M., Rajkumar, D. Edison, M. Sekar, S. Muhammad, & A. G. Al-Sehemi, Synthesis, growth, structural, thermal, third order nonlinear and computational studies of organic single crystal: 2-Amino4-picolinium 2-chloro-4-nitrobenzoate, Opt. Mater. 96 (2019) 109341. [8] H. Ishida, T. Fukunaga, and S. Kashino. "The 1: 1 complex of 2-chloro-4-nitrobenzoic acid and 1, 2, 3- benzotriazole." Acta Crystallographica Section E: Structure Reports Online, 58 (2002) 1083-1084. [9] V.G. Dmitriev, G.G. Gurzadyan, D.N. Nikogosyan, Handbook of nonlinear optical crystals, Springer, 2013. [10] M.K. Kumar, S. Sudhahar, P. Pandi, G. Bhagavannarayana, & R. M. Kumar, Studies of the structural and third-order nonlinear optical properties of solution grown 4-hydroxy3-methoxy-4′-N′-methylstilbazoliumtosylate monohydrate crystals, Opt. Mater. 36 (2014) 988-995. [11] B.M. Boaz, R.S. Selvaraj, K. S. Kumar, S.J. Das, Growth, microhardness, dielectric and photoconductivity characterization of a highly polarizable NLO material: Sodium p-nitrophenolate dehydrate (NO 2- C6H4-Ona. 2H2O), Indian J. Phys. 83 (2009) 1647-1657. [12] F. Stockmann, Negative Photoeffekte in halbleitern, Zeitschrift fur Physik, Bd. 143 (1955) 348-356. [13] P.R. Crippa, V. Cristofoletti, N. Romeo, A band model for Melanin deduced from optical absorption and photoconductivity experiments, Biochim. Biophys. Acta. 538 (1978) 164-170. [14] P. Karuppasamy, Muthu Senthil Pandian, and P. Ramasamy "Crystal growth and characterization of third order nonlinear optical piperazinium bis (4- hydroxybenzenesulphonate) (P4HBS) single crystal." Journal of Crystal Growth, 473 (2017) 39-54. [15] V. Sivasubramani, Muthu Senthil Pandian, and P. Ramasamy. "Comparative investigations of nonlinear optical (NLO) ammonium D, L-tartrate (AMT) single crystals grown by conventional and unidirectional method." AIP Conference Proceedings, 1 (2015) 100017. [16] A. Gupta, R. Rahman MK, R. O. M. U. Jauhar, V. Sivasubramani, N. Vijayan, G. Vinitha, and Lekha Nair. "Growth of L-asparagine monohydrate and its structural, optical, mechanical, thermal and electrical studies for nonlinear optical applications." Materials Research Express 6, 12 (2020) 125119. [17] V.N. Joshi, Photoconductivity, Marcel Dekker, New York, 1990. [18] M. Sheik-Bahae, A.A. Said, T.H. Wei, D.J. Hagan, E.W. Van Stryland, Sensitive measurement of optical nonlinearities using a single beam, Quant. Electron. 26 (1990) 760–769. [19] E.W. Van Stryland, M. Sheik-Bahae, Z-scan measurements of optical Nonlinearities Charact. Tech. Tabul. Org. Nonlinear Mater. 60 (1998) 655–692. [20] K. S. Ramesh, M. Saravanabhavan, M. Rajkumar, D. Edison, M. Sekar, S. Muhammad & A. G. Al-Sehemi, Synthesis, growth, structural, thermal, third order nonlinear and computational studies of organic single crystal: 2-Amino4-picolinium 2-chloro-4-nitrobenzoate, Opt. Mater. 96 (2019) 109341. [21] L. Chandra, J. Chandrasekaran, K. Perumal, & B. Babu, Third order nonlinear optical and electrical properties of new 2-aminopyridinium 2-chloro 4-nitrobenzoate single crystals, Optik. 127 (2016) 3206-3210. [22] A. Thirunavukkarsu, S. Sudhahar, G. Maheshwaran, T. Sujatha, P. R. Umarani, & R. M. Kumar, Synthesis, growth, structural, optical, thermal and mechanical properties of bis-benzotriazole trichloroacetic acid single crystals, Bull. Mater. Sci. 43 (2020) 1-11. [23] V. Sivasubramani, A. Raja, P. Karuppasamy, K. Ramachandran, Muthu Senthil Pandian, & P. Ramasamy, Crystal growth and characterization of semi-organic 2- amino-5-nitropyridinium bromide (2A5NPBr) single crystals for third-order nonlinear optical (NLO) applications, Appl. Phys. Res. A. 123 (2017) 780. [24] V. Parol, A. N. Prabhu, M. A. Taher, S. R. G. Naraharisetty, N. K. Lokanath & V. Upadhyaya, A third-order nonlinear optical single crystal of 3, 4-dimethoxy-substituted chalcone derivative with high laser damage threshold value: a potential material for optical power limiting, J. Mater. Sci: Mater. Electron. 31 (2020) 9133-9150. [25] D. Wang, T. Li, S. Wang, J. Wang, Z. Wang, X. Xu, & F. Zhang, Study on nonlinear refractive properties of KDP and DKDP crystals.RSC Adv. 6 (2016) 14490-14495. [26] Y.S. Zhou, E.B. Wang, J. Peng, J. Liu, C.W. Hu, R.D. Huang, X. You, Synthesis and the third-order optical nonlinearities of two novel charge-transfer complexes of a heteropoly blue type (C9H7NO=quinolin-8-ol) and (phen) 3 H7PMo12O40. Ch3CN. H2O (Phen=1, 10- phenanthroline). Polyhedron 18 (1999) 1419–1423. | ||
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