پیوندهای مفید
آمار
| تعداد نشریات | 21 |
| تعداد شماره‌ها | 610 |
| تعداد مقالات | 9,026 |
| تعداد مشاهده مقاله | 67,082,725 |
| تعداد دریافت فایل اصل مقاله | 7,656,153 |
پیش‌تغلیظ و اندازه‌گیری سودان IV به روش UA-d-μ-SPE با استفاده از گوشی هوشمند به عنوان یک ابزار اندازه‌گیری ساده در نمونه‌های غذایی و آبی | ||
| شیمى کاربردى روز | ||
| دوره 18، شماره 69، دی 1402، صفحه 69-84 اصل مقاله (970.77 K) | ||
| نوع مقاله: مقاله علمی پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22075/chem.2023.31190.2190 | ||
| نویسندگان | ||
| حمیدرضا حقگو قزلجه1؛ مریم رجبی* 1؛ علیرضا اصغری1؛ محمد بذرگر2 | ||
| 1دانشکده شیمی، دانشگاه سمنان، سمنان، ایران | ||
| 2شرکت شیمیایی پارس سولفیت، شهرک صنعتی کاوه، ساوه، مرکزی، ایران | ||
| تاریخ دریافت: 20 تیر 1402، تاریخ بازنگری: 07 شهریور 1402، تاریخ پذیرش: 11 شهریور 1402 | ||
| چکیده | ||
| در شیمی تجزیه استفاده از ساده ترین ابزار که امکان اندازه‌گیری در محل، هزینه کم و دستگاهوری ساده را فراهم نماید همواره مورد توجه پژوهشگران بوده است. در سال‌های اخیر استفاده از گوشی‌های هوشمند به عنوان یک وسیله‌ی در دسترس، می‌تواند این ویژگی ها را دارا باشد. در این پژوهش از جاذب Bi2O3/ZnO/Pd برای پیش‌تغلیظ و اندازه‌گیری رنگ سودان IV به عنوان یکی از رنگ‌های خانواده‌ی آزو در نمونه‌های غذایی و آبی با استفاده از گوشی هوشمند به روش ultrasonic assisted dispersive micro solid phase extraction (UA-d-μ-SPE) استفاده شد. ساختار این جاذب توسط آنالیزهای XRD، SEM و EDS مورد بررسی قرار گرفت. عواملی از قبیل مقدار جاذب (5.1 میلی‌گرم)، pH محلول نمونه (7.1)، حجم حلال شستشو دهنده (430.0 میکرولیتر) و زمان جذب (65 ثانیه) توسط روش طراحی مرکب مرکزی (CCD) و نوع حلال شستشو دهنده (متانول) و زمان واجذب (45 ثانیه) طبق روش یک پارامتر در زمان بهینه‌سازی شدند. در بهترین شرایط محدودیت تشخیص (LOD) برابر با 5.58 ng mL-1 و محدوده خطی (LDR) برای این رنگ برابر با 20-1100 ng mL-1 شد. فاکتور غنی سازی (EF) نیز 22.87 محاسبه شد. علاوه بر این انحراف استاندارد نسبی (RSD%) برابر با 3.91 با n=5 به دست آمد. | ||
| کلیدواژه‌ها | ||
| گوشی هوشمند؛ جاذب Bi2O3/ZnO/Pd؛ رنگ سودان IV؛ نمونه‌های غذایی و آبی؛ استخراج فاز جامد میکرو پخشی به کمک اولتراسونیک | ||
| عنوان مقاله [English] | ||
| Preconcentration and Measurement of Sudan IV Utilizing the UA-d-μ-SPE Method with a Smartphone as a Simple Measurement Tool in Food and Water Samples | ||
| نویسندگان [English] | ||
| Hamidreza Haghgoo Qezelje1؛ Maryam Rajabi1؛ Alireza Asghari1؛ Mohammad Bazregar2 | ||
| 1Faculty of Chemistry, Semnan University, Semnan, Iran | ||
| 2Parssulfite Chemical Company Iran, Markazi, Saveh, Kaveh industrial city | ||
| چکیده [English] | ||
| In analytical chemistry, the use of the simplest tool that provides the possibility of on-site measurement, low cost, and simple equipment has always been an area of interest for researchers. In recent years, the use of smartphones as an available tool can have these features. In this study, Bi2O3/ZnO/Pd adsorbent was used for preconcentration and measurement of Sudan IV color as one of the azo family colors in food and water samples, exploiting ultrasonic-assisted dispersive micro solid phase extraction (UA-d-μ-SPE) method along with a smartphone. The structure of this adsorbent was examined by XRD, SEM, and EDS analyses. Factors such as the amount of adsorbent (5.1 mg), sample solution pH (7.1), washing solvent volume (430.0 μL), and adsorption time (65 seconds) were optimized, utilizing central composite design (CCD) method. The type of washing solvent (methanol) and desorption time (45 seconds) were also optimized using the one-parameter-at-a-time method. In the best conditions, the limit of detection (LOD) was 5.58 ng mL-1, and the linear detection range (LDR) for this color was 20-1100 ng mL-1. The enrichment factor (EF) was also computed as 22.87. In addition, the relative standard deviation (RSD%) was acquired as 3.91 with n=5. | ||
| کلیدواژه‌ها [English] | ||
| Smartphone, Bi2O3/ZnO/Pd adsorbent, Sudan IV color, Food and water sample, Ultrasonic-assisted dispersive micro solid phase extraction (UA-d-μ-SPE) | ||
| مراجع | ||
|
[1] Li, L., Gao, H. W., Ren, J. R., Chen, L., Li, Y. C., Zhao, J. F., ... & Yuan, Y. (2007). Binding of Sudan II and IV to lecithin liposomes and E. coli membranes: insights into the toxicity of hydrophobic azo dyes. BMC Structural Biology, 7, 1-9.
[2] Kesiūnaitė, G., Linkevičiūtė, A., Naujalis, E., & Padarauskas, A. (2009). Matrix solid-phase dispersion extraction and UPLC determination of Sudan dyes in chili powder. Chromatographia, 70, 1691-1695.
[3] Rebane, R., Leito, I., Yurchenko, S., & Herodes, K. (2010). A review of analytical techniques for determination of Sudan I–IV dyes in food matrixes. Journal of Chromatography A, 1217(17), 2747-2757.
[4] Sciuto, S., Esposito, G., Dell'Atti, L., Guglielmetti, C., Acutis, P. L., & Martucci, F. (2017). Rapid screening technique to identify Sudan dyes (I to IV) in adulterated tomato sauce, chilli powder, and palm oil by innovative high-resolution mass spectrometry. Journal of food protection, 80(4), 640-644.
[5] Arghavani-Beydokhti, S., Rajabi, M., Bazregar, M., & Asghari, A. (2017). Centrifuge-free dispersive liquid–liquid microextraction based on the salting-out effect followed by high performance liquid chromatography for simple and sensitive determination of polycyclic aromatic hydrocarbons in water samples. Analytical Methods, 9(11), 1732-1740.
[6] Arghavani‐Beydokhti, S., Rajabi, M., & Asghari, A. (2018). Dissolvable layered double hydroxide nanoadsorbent‐based dispersive solid‐phase extraction for highly efficient and eco‐friendly simultaneous microextraction of two toxic metal cations and two anionic azo dyes in real samples. Applied Organometallic Chemistry, 32(5), e4279.
[7] Arghavani-Beydokhti, S., Rajabi, M., & Asghari, A. (2017). Combination of magnetic dispersive micro solid-phase extraction and supramolecular solvent-based microextraction followed by high-performance liquid chromatography for determination of trace amounts of cholesterol-lowering drugs in complicated matrices. Analytical and Bioanalytical Chemistry, 409, 4395-4407.
[8] Arghavani-Beydokhti, S., Rajabi, M., & Asghari, A. (2018). Application of syringe to syringe dispersive micro-solid phase extraction using a magnetic layered double hydroxide for the determination of cadmium (II) and lead (II) ions in food and water samples. Analytical Methods, 10(11), 1305-1314.
[9] Rajabi, M., Arghavani-Beydokhti, S., Barfi, B., & Asghari, A. (2017). Dissolvable layered double hydroxide as an efficient nanosorbent for centrifugeless air-agitated dispersive solid-phase extraction of potentially toxic metal ions from bio-fluid samples. Analytica chimica acta, 957, 1-9.
[10] Bashir, K., Chen, G., Han, J., Shu, H., Cui, X., Wang, L., ... & Fu, Q. (2020). Preparation of magnetic metal organic framework and development of solid phase extraction method for simultaneous determination of fluconazole and voriconazole in rat plasma samples by HPLC. Journal of Chromatography B, 1152, 122201.
[11] Asghari, A., ARGHAVANI, B. S., & Rajabi, M. (2016). Solid phase extraction of heavy metal ions in environmental samples on chemically bonded single-walled carbon nanotubes with 2-((3-silylpropylimino) methyl) phenol.
[12] Chisvert, A., Cárdenas, S., & Lucena, R. (2019). Dispersive micro-solid phase extraction. TrAC Trends in Analytical Chemistry, 112, 226-233.
[13] Alizadeh, R., Faal, A. Y., & Seidi, S. (2021). Development of ultrasound assisted dispersive micro solid phase extraction based on CuO nanoplate-polyaniline composite as a new sorbent for insecticides analysis in wheat samples. Microchemical Journal, 168, 106422.
[14] Tadese, M., Amde, M., Leta Danno, B., Benti, L., & Megersa, N. (2023). Magnetised and sulfide functionalised zinc oxide nanocomposite for dispersive micro-solid-phase extraction of lead (II) and cadmium (II) in water samples. International Journal of Environmental Analytical Chemistry, 103(5), 1203-1221.
[15] Shaikh, F., Panhwar, Q. K., Balouch, A., Ali, S., Panhwar, W. A., & Sheikh, F. (2022). Synthesis of zinc oxide nanoparticles and their functionalisation with chrysin: Exploration of its applications. International Journal of Environmental Analytical Chemistry, 102(7), 1662-1671.
[16] Hessien, M. (2022). Recent progress in zinc oxide nanomaterials and nanocomposites: From synthesis to applications. Ceramics International, 48(16), 22609-22628.
[17] Jan, T., Azmat, S., Wahid, B., Adil, M., Alawadhi, H., Mansoor, Q., ... & Ismail, M. (2018). Chemically synthesized ZnO-Bi2O3 (BZO) nanocomposites with tunable optical, photoluminescence and antibacterial characteristics. Materials Science in Semiconductor Processing, 84, 71-75.
[18] Abouhaswa, A. S., & Kavaz, E. (2020). Bi2O3 effect on physical, optical, structural and radiation safety characteristics of B2O3Na2O-ZnOCaO glass system. Journal of Non-Crystalline Solids, 535, 119993.
[19] Saadati, M. (2021). Smartphone-based digital image analysis for determination of some food dyes in commercial products. Food Analytical Methods, 14(11), 2367-2374.
[20] Kahu, S. Y., Raut, R. B., & Bhurchandi, K. M. (2019). Review and evaluation of color spaces for image/video compression. Color Research & Application, 44(1), 8-33.
[21] Bavandpour, R., Rajabi, M., & Karimi-Maleh, H. (2020). Ultrasensitive electroanalytical sulfisoxazole sensors amplified with Pd-doped ZnO nanoparticles and modified with 1-hexyl-3-methyl imidazolium bis (trifluoromethylsulfonyl) imide. New Journal of Chemistry, 44(26), 11125-11130.
[22] Ansari, S., Ansari, M. S., Satsangee, S. P., & Jain, R. (2021). Bi2O3/ZnO nanocomposite: Synthesis, characterizations and its application in electrochemical detection of balofloxacin as an anti-biotic drug. Journal of Pharmaceutical Analysis, 11(1), 57-67.
[23] Bazregar, M., Rajabi, M., Yamini, Y., Arghavani-Beydokhti, S., & Asghari, A. (2018). Centrifugeless dispersive liquid-liquid microextraction based on salting-out phenomenon followed by high performance liquid chromatography for determination of Sudan dyes in different species. Food chemistry, 244, 1-6.
[24] Zulkifli, Z. A., Razak, K. A., Rahman, W. N. W. A., & Abidin, S. Z. (2018, August). Synthesis and characterisation of bismuth oxide nanoparticles using hydrothermal method: the effect of reactant concentrations and application in radiotherapy. In Journal of Physics: Conference Series (Vol. 1082, p. 012103). IOP Publishing.
[25] Hemmati, M., Rajabi, M., & Asghari, A. (2017). A twin purification/enrichment procedure based on two versatile solid/liquid extracting agents for efficient uptake of ultra-trace levels of lorazepam and clonazepam from complex bio-matrices. Journal of Chromatography A, 1524, 1-12.
[26] Moreno-González, D., Jáč, P., Švec, F., & Nováková, L. (2020). Determination of Sudan dyes in chili products by micellar electrokinetic chromatography-MS/MS using a volatile surfactant. Food chemistry, 310, 125963.
[27] Chen, J., Li, X., Huang, A., Deng, W., & Xiao, Y. (2021). Nonionic surfactants based hydrophobic deep eutectic solvents for liquid–liquid microextraction of Sudan dyes in tomato chili sauces. Food Chemistry, 364, 130373.
[28] Ozak, S. S., & Yılmaz, Y. (2020). Ultrasound-assisted hydrophobic deep eutectic solvent based solid-liquid microextraction of Sudan dyes in spice samples. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 236, 118353.
[29] Adjei, J. K., Ahormegah, V., Boateng, A. K., Megbenu, H. K., & Owusu, S. (2020). Fast, easy, cheap, robust and safe method of analysis of Sudan dyes in chilli pepper powder. Heliyon, 6(10).
[30] Ge, D., Shan, Z., Pang, T., Lu, X., & Wang, B. (2021). Preparation of new hydrophobic deep eutectic solvents and their application in dispersive liquid–liquid microextraction of Sudan dyes from food samples. Analytical and Bioanalytical Chemistry, 413(15), 3873-3880.
[31] Zhou, Q., Wu, Y., Yuan, Y., Zhou, X., Wang, H., Tong, Y., ... & Sheng, X. (2019). Determination of Sudan red contaminants at trace level from water samples by magnetic solid-phase extraction using Fe@ NiAl-layered double hydroxide coupled with HPLC. Environmental Sciences Europe, 31, 1-10. | ||
|
آمار تعداد مشاهده مقاله: 345 تعداد دریافت فایل اصل مقاله: 439 |
||