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توسعه و بهینه‌سازی سنتز MIL-101(Cr) به روش فراصوت با استفاده از روش سطح پاسخ | ||
| شیمى کاربردى روز | ||
| دوره 19، شماره 71، تیر 1403، صفحه 223-246 اصل مقاله (1.61 M) | ||
| نوع مقاله: مقاله علمی پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22075/chem.2024.30396.2167 | ||
| نویسندگان | ||
| احمد نیک سرشت* ؛ حجت الله نورمحمدی | ||
| گروه شیمی، دانشگاه پیام نور،تهران، ایران. | ||
| تاریخ دریافت: 30 فروردین 1402، تاریخ بازنگری: 13 دی 1402، تاریخ پذیرش: 20 دی 1402 | ||
| چکیده | ||
| چارچوب MIL-101(Cr) یکی از موردمطالعه‌ترین چارچوب‌های آلی-فلزی با پایه کروم است. این چارچوب از یون کروم و لیگاند ترفتالیک‌اسید تشکیل‌شده‌است. در این مطالعه، به‌منظور توسعه روش‌های کارآمد سنتز جایگزین، از روش فراصوت سنتز استفاده‌شد. بهینه‌سازی بازده این چارچوب آلی-فلزی بامطالعه دو پارامتر اساسی، یعنی دما و زمان، با استفاده از روش سطح پاسخ انجام‌شد. تأثیر این پارامترها از طریق طراحی مرکب مرکزی (CCD) ، بهینه‌شده و رفتار آن‌ها با استفاده از آنالیز واریانس مورد تجزیه و تحلیل قرار‌گرفت. یک معادله درجه دوم برای پیش‌بینی رفتار فرآیند در شرایط مختلف با R2 برابر با 9998/0 ارائه‌شده‌است. که نشان‌دهنده همپوشانی مناسب داده‌های تجربی و مقادیر پیش‌بینی‌شده توسط مدل ارائه‌شده، برای میزان بهینه بازده است. پارامترهای حاصل از آنالیز واریانس، نشان‌می‌دهند که زمان اثر معنی‌دارتر و نقش مؤثرتری در مدل ایفا‌می‌کند. ساختار نانوترکیب تهیه‌شده، با استفاده از تکنیک‌های طیف‌سنجی پراش پرتوی ایکس، طیف‌سنج مادون‌قرمز تبدیل فوریه، آنالیز توزین حرارتی، میکروسکوپ الکترونی روبشی و اندازه‌گیری سطح ویژه مواد و تخلخل‌سنجی جذب و واجذب نیتروژن به روش BET شناسایی‌شد. این ماده یک سطح ویژه بسیار بالا (m2.g-1 2143)، حجم حفره بزرگ (cm3.g-1 8/0)، پایداری حرارتی/شیمیایی/آب خوب دارد. همچنین نتایج حاصل از سنتز با استفاده از حمام فراصوت، نشان‌داد که ذرات دارای حفره‌های ریز متخلخل، قفس‌های مزوپور و شکل هشت‌وجهی یکنواخت با اندازه متوسط 125 تا 260 نانومتر هستند. میزان مصرف انرژی تابش فراصوت، بسیار کمتر از روش‌های هیدروترمال و سولوترمال است. بنابراین می‌توان گفت که فن‌آوری فراصوت، سبزتر، سریع‌تر و کارآمدتر از روش‌های گرمایش الکتریکی مرسوم است. | ||
| کلیدواژه‌ها | ||
| MIL-101 (Cr)؛ امواج فراصوت؛ روش سطح پاسخ؛ چارچوب‌های آلی-فلزی؛ ترفتالیک اسید و آنالیز واریانس | ||
| عنوان مقاله [English] | ||
| Development and Optimization Synthesis of MIL-101(Cr) by Ultrasound Irradiation Using Response Surface Methodology | ||
| نویسندگان [English] | ||
| Ahmad Nikseresht؛ Hojatolah Normohamadi | ||
| Department of Chemistry; Payame Noor University (PNU); P.OBox; 19395-4697 Tehran; Iran | ||
| چکیده [English] | ||
| MIL-101(Cr) stands as one of the extensively researched chromium-based metal–organic frameworks, comprised of chromium metal ions and terephthalic acid ligands. This study introduces an innovative approach to MIL-101(Cr) synthesis by employing ultrasound (UTS) irradiation. Our primary objective revolved around optimizing key operational parameters, namely time and temperature, using the central composite design method. Subsequently, we conducted an in-depth analysis using variance analysis to understand their respective impacts. To predict process behaviour, we developed quadratic equations under varying conditions, achieving a remarkable R2 value of 0.9998 to relate parameters and synthesis yield. Results revealed a more pronounced influence of time variation compared to temperature on the synthesis process. Moreover, we subjected the synthesized MIL-101(Cr) to rigorous characterization using FT-IR, XRD, SEM, TGA, and N2 physisorption techniques. Our findings showcased the synthesized MIL-101(Cr) possessing exceptional characteristics, including an ultra-high specific surface area (2143 m2. g-1), substantial pore size (0.8 cm3.g-1), and excellent thermal, chemical, and water stability. Further examination indicated the presence of microporous windows, mesoporous cages, and uniform octahedral particles ranging in size between 125-260 nm. Notably, our study emphasized the energy efficiency of UTS irradiation over conventional electric (CE) heating, highlighting its potential as a quicker, more efficient, and environmentally friendly alternative to conventional synthesis methods. | ||
| کلیدواژه‌ها [English] | ||
| Mil-101(Cr), Ultrasonic irradiation, Response surface methodology, Metal-organic framework, Terephthalic acid, Analysis of variance | ||
| مراجع | ||
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