Kazazi, Mahdi, Kazemi, Soheila, Koozegar Kaleji, Behzad. (1405). Binder-Free Mesoporous Vanadium Oxide Electrode: Anodic Electrodeposition, Characterization, and Supercapacitor Application. هنرهای کاربردی, 6(3), 249-255. doi: 10.22075/ppam.2026.40173.1198
Mahdi Kazazi; Soheila Kazemi; Behzad Koozegar Kaleji. "Binder-Free Mesoporous Vanadium Oxide Electrode: Anodic Electrodeposition, Characterization, and Supercapacitor Application". هنرهای کاربردی, 6, 3, 1405, 249-255. doi: 10.22075/ppam.2026.40173.1198
Kazazi, Mahdi, Kazemi, Soheila, Koozegar Kaleji, Behzad. (1405). 'Binder-Free Mesoporous Vanadium Oxide Electrode: Anodic Electrodeposition, Characterization, and Supercapacitor Application', هنرهای کاربردی, 6(3), pp. 249-255. doi: 10.22075/ppam.2026.40173.1198
Kazazi, Mahdi, Kazemi, Soheila, Koozegar Kaleji, Behzad. Binder-Free Mesoporous Vanadium Oxide Electrode: Anodic Electrodeposition, Characterization, and Supercapacitor Application. هنرهای کاربردی, 1405; 6(3): 249-255. doi: 10.22075/ppam.2026.40173.1198

Binder-Free Mesoporous Vanadium Oxide Electrode: Anodic Electrodeposition, Characterization, and Supercapacitor Application

Progress in Physics of Applied Materials
دوره 6، شماره 3 - شماره پیاپی 12، زمستان 2026، صفحه 249-255    اصل مقاله (1.42 M)
نوع مقاله: Original Article
شناسه دیجیتال (DOI): 10.22075/ppam.2026.40173.1198
نویسندگان
Mahdi Kazazi* ؛ Soheila Kazemi؛ Behzad Koozegar Kaleji
Department of Materials Engineering, Faculty of Engineering, Malayer University, Malayer, Iran
چکیده
Mesoporous vanadium oxide (V2O5) was galvanostatically electrodeposited into nickel foam to obtain a binder-free electrode with a three-dimensional (3D) porous structure for supercapacitive performance. The anodic electrodeposition process was performed using an aqueous solution of vanadyl sulfate, which was completed by calcination treatment. XRD and FTIR confirmed the formation of the orthorhombic V2O5 structure, also and FESEM and BET analysis revealed the 3D mesoporous structure of the electrode material. The supercapacitive performance of the fabricated electrode was evaluated using CV, GCD, and EIS examinations in lithium perchlorate electrolyte. The charge storage mechanism involved the intercalation/de-intercalation of lithium ions within the electrode structure, resulting in a vanadium valence shift between V4+/V5+. The prepared electrode showed an acceptable capacitance of 496 F g-1 at a rate of 1 A g-1, a suitable rate performance with a capacitance retention of 36.1%, and good cyclability with a capacitance retention of 85.2% after 2000 cycles. The resulting porous structure shortens the diffusion path of electrolyte ions to the active material, while the removal of the insulating binder reduces its the internal resistance, both of which improve the kinetics of electrochemical reactions. These results demonstrate the promise of vanadium oxide as an advanced electrode material for next-generation high-performance energy storage devices.  
کلیدواژه‌ها
Vanadium oxide؛ Mesoporous structure؛ Electrodeposition؛ Binder-free electrode؛ Supercapacitors
مراجع
آمار
تعداد مشاهده مقاله: 132
تعداد دریافت فایل اصل مقاله: 222
دانشگاه سمنان
پیوندهای مفید
آمار
تعداد نشریات22
تعداد شماره‌ها718
تعداد مقالات10,319
تعداد مشاهده مقاله72,324,639
تعداد دریافت فایل اصل مقاله64,048,131