پیوندهای مفید
آمار
| تعداد نشریات | 21 |
| تعداد شماره‌ها | 628 |
| تعداد مقالات | 9,179 |
| تعداد مشاهده مقاله | 67,527,494 |
| تعداد دریافت فایل اصل مقاله | 8,062,143 |
افزایش بازدهی هیدروژن خالص تولیدی در فرآیند حلقه شیمیایی متانول با استفاده از آرایش دولایه ای کاتالیست حامل اکسیژنی | ||
| شیمى کاربردى روز | ||
| دوره 19، شماره 71، تیر 1403، صفحه 49-68 اصل مقاله (1.21 M) | ||
| نوع مقاله: مقاله علمی پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22075/chem.2023.28374.2098 | ||
| نویسندگان | ||
| حسین خانی؛ ناهید خندان* ؛ محمدحسن ایکانی؛ علی الیاسی | ||
| پژوهشکده فناوری های شیمیایی، سازمان پژوهش های علمی صنعتی ایران، تهران، ایران | ||
| تاریخ دریافت: 20 شهریور 1401، تاریخ بازنگری: 17 مرداد 1402، تاریخ پذیرش: 13 شهریور 1402 | ||
| چکیده | ||
| طرح تولید H2 خالص برای مصارف پیل سوختی پلیمری با ریفرمینگ حلقه شیمیایی متانول و حامل اکسیژنی 0.3CoFe2O4-0.4ZrO2 در راکتور میکروکانال مورد مطالعه قرار گرفت و نتایج این تحقیق نشان داد تولید H2 خالص تنها در صورت کنترل رسوب کک امکانپذیر است. با بهینه سازی زمان واکنش احیا به 7 دقیقه، رسوب کک، کنترل و جریان H2 خالص با بازدهی متوسط 6/2% تولید شد که نتیجه ای جالب بود و تاکنون این درجه خلوص با روش حلقه شیمیایی متانول گزارش نشده است. برای افزایش بازدهی در این طرح، دو لایه کاتالیست بصورت پوشش یک لایه اضافه با خاصیت مقاومت بالا به کک و واکنش پذیری مناسب با متانول با ترکیب 10% از NiO/MgAl2O4 بر روی 0.3CoFe2O4-0.4ZrO2 پیشنهاد شد. بهینه سازی زمان واکنش با استفاده از حامل اکسیژنی دولایه ای نشان داد استفاده از غلظت 20% نیکل در زمان واکنش 11 دقیقه، سبب افزایش بازدهی H2 با خلوص 100% شد که به مقدار 42% در آرایش دولایه ای نسبت به حالت تک لایه افزایش داشته و یک نتیجه امیدبخش برای حامل اکسیژنی دولایه ای در این فرآیند می باشد. | ||
| کلیدواژه‌ها | ||
| "تولید هیدروژن خالص"؛ "کاتالیست دولایه"؛ "فرایند حلقه شیمیایی"؛ "حامل اکسیژنی"؛ "ارتقاء بازدهی" | ||
| عنوان مقاله [English] | ||
| Increasing the yield of pure hydrogen generated in the chemical loop reforming of methanol by using the oxygen carrier catalyst bi- layer arrangement | ||
| نویسندگان [English] | ||
| Hossein Khani؛ Nahid Khandan؛ Mohammad Hasan Eikani؛ Ali Eliassi | ||
| Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), Tehran, Iran | ||
| چکیده [English] | ||
| The production of pure H2 for polymer fuel cells was studied by the chemical loop reforming of methanol in the presence of 0.3CoFe2O4-0.4ZrO2 as an oxygen carrier in a micro-channel reactor. The results of this study showed that the production of pure H2 is possible only if the coke deposition is controlled. By optimizing the reduction time to 7 minutes, the coke deposition controlled and pure H2 flow was produced with an average yield of 2.6%, which was an interesting result and so far this degree of purity of H2 has not been reported by the chemical loop reforming of methanol. To increase the yield of pure H2 in this study, a two-layer catalyst concept is proposed in the form of an additional layer coating with high resistance to coke and suitable reactivity with methanol from NiO/MgAl2O4 to 10% on 0.3CoFe2O4-0.4ZrO2 layer. Optimization of various parameters using the concept of double-layer oxygen carrier showed that the use of 20% nickel concentration with a reduction time of 11 minutes increased the yield of H2 with 100% purity, which increased by 42% in the double-layer arrangement compared to the single-layer state, and it is a promising result for the concept of bi-layer oxygen carrier in this process. | ||
| کلیدواژه‌ها [English] | ||
| " Production of pure hydrogen", "bi-layer catalyst", "Chemical loop process", "Oxygen carrier", "Yield enhancement" | ||
| مراجع | ||
|
[1] Wan, Z., Tao, Y., Shao, J., Zhang, Y., You, H. (2021). Ammonia as an effective hydrogen carrier and a clean fuel for solid oxide fuel cells. Energy Convers. Manag., 228(113729), 1-18.
[2] Wang, K., Men, Y., Liu, W., Zhang, J. (2022). Recent progress in catalytical CO purification of H2-rich reformate for proton exchange membrane fuel cells. Int. J. Hydrogen Energy, 48(64), 25100-25118.
[3] Seyedzadeh, Z. Atabaki, F. Ghaemi, N. Nasiri M. (2019). Composite membranes for proton exchange membrane fuel cells based on methyl methacrylate-co - maleimide / phosphotungstic acid. Applied Chemistry, 13(49), 65–78. (in persion)
[4] Rahil, A., Gammon, R., Brown, N. (2018). Flexible operation of electrolyser at the garage forecourt to support grid balancing and exploitation of hydrogen as a clean fuel. Res. Transp. Econ., 70,125–138.
[5] Sahebdelfar, S., Ravanchi, M. T. (2022). Carbon monoxide clean-up of the reformate gas for PEM fuel cell applications: A conceptual review. Int. J. Hydrogen Energy, 48(64), 24709-24729.
[6] Ruocco, C., Palma, V., Ricca, A. (2019). Hydrogen production by oxidative reforming of ethanol in a fluidized bed reactor using a Pt Ni/CeO2SiO2 catalyst. Int. J. Hydrogen Energy, 44(25),12661–70.
[7] Shiva Kumar, S., Himabindu, V. (2019). Hydrogen production by PEM water electrolysis – A review. Mater. Sci. Energy Technol., 2(3), 442–54.
[8] Ghaffarinead, A., Tabatabaei, A., Sohrabi, B., Salahandish, R. (2019). The effect of surfactants on electrochemical hydrogen production. Applied Chemistry, 14(50), 25–40. (in persion)
[9] Luo, M., Yi, Y., Wang, S., Wang, Z., Du, M., Pan, J., et al. (2018). Review of hydrogen production using chemical-looping technology. Renew. Sustain. Energy Rev., 81, 3186–214.
[10] Voitic, G., Nestl, S., Malli, K., Wagner, J., Bitschnau, B., Mautner, F-A., et al. (2016). High purity pressurised hydrogen production from syngas by the steam-iron process. RSC Advances, 6(58), 53533–41.
[11] Hormilleja, E., Durán, P., Plou, J., Herguido, J., Peña, J. A. (2014). Hydrogen from ethanol by steam iron process in fixed bed reactor. Int. J. Hydrogen Energy, 39(10), 5267–73.
[12] Yang, J., Cai, N., Li, Z. (2008). Hydrogen Production from the Steam−Iron Process with Direct Reduction of Iron Oxide by Chemical Looping Combustion of Coal Char. Energy & Fuels, 22(4), 2570–9.
[13] Gupta, P., Velazquez-Vargas, L. G., Fan, L-S. (2007). Syngas Redox (SGR) Process to Produce Hydrogen from Coal Derived Syngas. Energy & Fuels, 21(5), 2900–8.
[14] Li, F., Kim, H. R., Sridhar, D., Wang, F., Zeng, L., Chen, J., et al. (2009). Syngas Chemical Looping Gasification Process: Oxygen Carrier Particle Selection and Performance. Energy & Fuels, 23(8), 4182–9.
[15] Urasaki, K., Tanimoto, N., Hayashi, T., Sekine, Y., Kikuchi, E., Matsukata, M. (2005). Hydrogen production via steam–iron reaction using iron oxide modified with very small amounts of palladium and zirconia. Appl. Catal. A Gen., 288(1-2), 143–8.
[16] Galvita, V., Sundmacher, K. (2005). Hydrogen production from methane by steam reforming in a periodically operated two-layer catalytic reactor. Appl. Catal. A Gen., 289(2), 121–7.
[17] Dharanipragada, N. V. R. A., Galvita, V. V., Poelman, H., Buelens, L. C., Detavernier, C., Marin, G. B. (2018). Bifunctional Co- and Ni- ferrites for catalyst-assisted chemical looping with alcohols. Appl. Catal. B Environ., 222, 59–72.
[18] Cocchi, S., Mari, M., Cavani, F., Millet, J-M. M. (2014). Chemical and physical behavior of CoFe2O4 in steam–iron process with methanol. Appl. Catal. B Environ., 152–153, 250–61.
[19] Crocellà, V., Cavani, F., Cerrato, G., Cocchi, S., Comito, M., Magnacca, G., et al. (2012). On the Role of Morphology of CoFeO 4 Spinel in Methanol Anaerobic Oxidation. J. Phys. Chem. C, 116(28), 14998–5009.
[20] Góral, A., Czeppe, T., Berent, K. (2019). Oxidation behaviour of thin Ni/Al2O3 nanocomposite coatings electrodeposited on steel substrate. Surf. Coatings Technol., 369(15), 95–104.
[21] Wang, H-S., Huang, K-Y., Huang, Y-J., Su, Y-C., Tseng, F-G. (2015). A low-temperature partial-oxidation-methanol micro reformer with high fuel conversion rate and hydrogen production yield. Appl. Energy, 138, 21–30.
[22] Parsaee, A., Eliassi, A., Ranjbar, M., Kashi, E. (2018). Preparation of Cu-Zn-Ce-Al Spinel Catalyst for Hydrogen Production in Micro-Channel Reactor and Considering the Geometrical Effects of Micro-Channels on Velocity Distribution. Applied Chemistry, 12(45), 71–82. (in persion)
[23] Khoshrooyan, L., Eliassi, A., Ranjbar, M. (2016). Effects of catalyst particle size on methanol dehydration at different temperatures and weight hourly space velocities. J. Particle Science and Technology, 2(1), 41–7. (in persion)
[24] Ramasubramanian, V., Ramsurn, H., Price, G. L. (2020). Hydrogen production by catalytic decomposition of methane over Fe based bi-metallic catalysts supported on CeO2–ZrO2. Int. J. Hydrogen Energy, 45(21), 12026–36.
[25] Li, Z., Wachemo, A. C., Yuan, H., Korai, R. M., Li, X. (2020). Improving methane content and yield from rice straw by adding extra hydrogen into a two-stage anaerobic digestion system. Int. J. Hydrogen Energy, 45(6), 3739–49.
[26] Khani, H., Khandan, N., Eikani, M. H., Eliassi, A. (2022). Production of clean hydrogen fuel on a bifunctional iron catalyst via chemical loop reforming of methanol. Fuel, 334, 126607.
[27] Khani, H., Khandan, N., Eikani, M. H., Eliassi, A. (2023). Investigation of synthesized Fe2O3 and CuO–Fe2O3 for pure hydrogen production by chemical-loop reforming of methanol in a micro-channel reactor. Int. J. Hydrogen Energy, 48(16), 6436–50.
[28] Sun, Z., Zhang, X., Li, H., Liu, T., Sang, S., Chen, S., et al. (2020). Chemical looping oxidative steam reforming of methanol: A new pathway for auto-thermal conversion. Appl. Catal. B Environ., 269, 118758.
[29] Zeng, L., Wei, D., Toan, S., Sun, Z., Sun, Z. (2022). Sorption-enhanced chemical looping oxidative steam reforming of methanol for on-board hydrogen supply. Green Energy Environ., 7(1):145–55. | ||
|
آمار تعداد مشاهده مقاله: 121 تعداد دریافت فایل اصل مقاله: 132 |
||