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تأثیر موقعیت اتم نیتروژن پیریدینی در لیگاند بازشیف سه دندانه NN'O بر نوع پلیمر کوئوردیناسیونی کمپلکس مس (II): یک بررسی بلورشناسی | ||
| شیمى کاربردى روز | ||
| دوره 19، شماره 72، مهر 1403، صفحه 283-304 اصل مقاله (1.48 M) | ||
| نوع مقاله: مقاله علمی پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22075/chem.2024.33885.2266 | ||
| نویسندگان | ||
| کیمیا فروغی1؛ هادی امیری رودباری* 1؛ رضا آزادبخت2 | ||
| 1گروه شیمی معدنی، دانشکده شیمی، دانشگاه اصفهان، اصفهان، ایران | ||
| 2گروه شیمی معدنی، دانشکده شیمی و علوم نفت، دانشگاه بوعلی سینا، همدان، ایران | ||
| تاریخ دریافت: 13 اردیبهشت 1403، تاریخ بازنگری: 21 مهر 1403، تاریخ پذیرش: 14 آبان 1403 | ||
| چکیده | ||
| پلیمرهای کوئوردیناسیونی (CPs) با استفاده از لیگاندهای آلی پل‌ساز و یون‌های فلزی تهیه می‌شوند که با توجه به شکل هندسی کوئوردینانسی فلز، لیگاندهای پل‌ساز و اتم‌های دهنده‌ی موجود در این لیگاندها، تشکیل ساختارهای پلیمری مختلف یک‌بعدی، دوبعدی یا شبکه‌ی پلیمری سه‌بعدی امکان پذیر است. به منظور بررسی تأثیر موقعیت اتم نیتروژن پیریدینی در لیگاند بازشیف سه دندانه NN'O بر نوع پلیمرهای کوئوردیناسیونی، دو کمپلکس مس تهیه شد. لیگاند HL2با تکنیکهای IR، NMR و آنالیز عنصری، و کمپلکسها نیز با تکنیکهای IR، آنالیز عنصری و پراش پرتو ایکس مورد بررسی و شناسایی قرار گرفتند. داده‌های ساختاری کمپلکسهای مس نشان داد که با تغییر اتم نیتروژن پیریدنی از موقعیت 3 به 4 در لیگاند بازشیف، ساختار کمپلکس مس از حالت دو بعدی به سه بعدی تغییر مییابد. بررسی برهمکنشهای بینمولکولی و درونمولکولی با برنامه‌ی NCI نشان می‌دهد که برهمکنش‌ها در دو مولکول از نوع پیوند هیدروژنی، پیوند هالوژنی، CH…π، انباشتگیπ…π ، فلز...π و جفت الکترون غیر پیوندیπ… است. | ||
| کلیدواژه‌ها | ||
| پلیمرهای کوئوردیناسیونی؛ ترکیبات باز شیف؛ کمپلکس مس؛ هالوژن؛ بلورشناسی | ||
| عنوان مقاله [English] | ||
| The Effect of the Position of the Pyridine Nitrogen Atom in the Tridentate NN'O Schiff Base Ligand on the Type of Coordination Polymer of the Copper(II) Complex: A Crystallographic Study | ||
| نویسندگان [English] | ||
| Kimia Forooghi1؛ Hadi Amiri Rudbari1؛ Reza Azadbakht2 | ||
| 1Department of Chemistry, Faculty of Chemistry, University of Isfahan, Isfahan, Iran | ||
| 2Department of Chemistry, Faculty of Chemistry and Petroleum Sciences, University of Bu-Ali Sina, Hamedan, Iran | ||
| چکیده [English] | ||
| Coordination polymers (CPs) are synthesized using bridging organic ligands and metal ions, depending on the geometric coordination of the metal, the bridging ligands, and the donor atoms present in these ligands, various one-, two-, or three-dimensional polymeric structures can form. To investigate the effect of the position of the pyridine nitrogen atom in the tridentate NN'O Schiff base ligand on the type of coordination polymers, two copper complexes were prepared. The ligand HL2 was characterized using IR, NMR, and elemental analysis, while the complexes were analyzed and identified using IR, elemental analysis, and X-ray diffraction techniques. The structural data of the copper complexes indicated that changing the pyridine nitrogen from position 3 to position 4 in the Schiff base ligand altered the structure of the copper complex from two-dimensional to three-dimensional. Analysis of inter- and intramolecular interactions using the NCI program shows that the interactions in both molecules are of the hydrogen bonding, halogen bonding, CH…π, π…π stacking, metal…π, and lone-pair…π type. | ||
| کلیدواژه‌ها [English] | ||
| Coordination Polymers, Schiff base Compounds, Copper Complex, Halogen, Crystallography | ||
| مراجع | ||
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