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تولید بیودیزل با استفاده از نانوکامپوزیت جدیدی از چارچوب آلی-فلزی مبتنی بر Fe (ΙΙΙ) و اسید فسفومولیبدیک به عنوان یک کاتالیزور سبز و ناهمگن | ||
| شیمى کاربردى روز | ||
| دوره 18، شماره 67، تیر 1402، صفحه 31-50 اصل مقاله (1.46 M) | ||
| نوع مقاله: مقاله علمی پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22075/chem.2022.27186.2072 | ||
| نویسندگان | ||
| ثریا پرک1؛ احمد نیک سرشت* 2؛ محمد علی کرمی1 | ||
| 1گروه شیمی، واحد ایلام، دانشگاه آزاد اسلامی، ایلام، ایران | ||
| 2گروه شیمی، دانشگاه پیام نور،تهران، ایران | ||
| تاریخ دریافت: 03 خرداد 1401، تاریخ بازنگری: 28 شهریور 1401، تاریخ پذیرش: 06 مهر 1401 | ||
| چکیده | ||
| در این مطالعه، سنتز نمونه‌های چارچوب آلی-فلزی بر پایه آهن (Ⅲ(، MIL-53(Fe)، همراه با فرآیند محصورسازی اسید فسفومولیبدیک با تابش فراصوت در دمای محیط و فشار اتمسفر انجام می‌شود. آنالیز و تحلیل دقیق نتایج نشان‌داد که ساختار کگینی هتروپلی‌اسید H3PMo برهمکنش‌های الکتروستاتیک قوی با شبکه آهن (III) ایجادکرده، که نقش مهمی را در کاهش لیچینگ (شسته شدن) از ترکیب ایفا می‌نمایند. ساختار نانوکامپوزیت تهیه‌شده‌ی جدید، با استفاده از تکنیک‌های پراش پرتوی ایکس، طیف‌سنج مادون قرمز تبدیل فوریه، آنالیز حرارتی همزمان، طیف‌سنج نشر اتمی پلاسمای جفت‌شده القایی، طیف‌سنجی پراش انرژی پرتو ایکس و میکروسکوپ الکترونی روبشی شناسایی شد. فعالیت کاتالیزوری نانوکامپوزیتهای تهیه شده، فسفومولیبدیک اسیدکپسوله‌شده در چارچوب آلی-فلزی بر پایه آهن (Ⅲ(، PMA@MIL-53(Fe)، از طریق واکنش استری‌شدن اسید اولئیک با اتانول تحت تابش فراصوت مورد آزمایش قرارگرفت. فرآیند تولید بیودیزل با استفاده از مقادیر مشخصی از نسبت مولی اسید اولئیک و اتانول، نانوکامپوزیتPMA@MIL-53(Fe) به عنوان کاتالیزور (50-200 میلی گرم) که حاوی مقادیر مختلف اسید فسفومولیبدیک، PMA (0-40%) است، با میزان مشخصی از انرژی مصرفی برحسب وات، در زمان‌های مختلف (5-25 دقیقه) در دمای محیط، تحت شرایط اولتراسوند بهینه‌سازی شد. نتایج به‌دست آمده حاکی از آن است که نمونه‌های کامپوزیت سنتزشده فعالیت کاتالیزوری عالی را نشان می‌دهند. و همچنین کارایی کاتالیزورهای ناهمگن همراه با تابش فراصوت برای تولید بیودیزل بطور چشمگیری افزایش می‌یابد. نتایج نشان داد که افزایش همه پارامترها موجب افزایش بازدهی فرایند تا مقادیر 98 درصد می‌شوند. | ||
| کلیدواژه‌ها | ||
| کاتالیزورناهمگن؛ اسید فسفومولیبدیک؛ چارچوب آلی-فلزی؛ PMA@MIL-53(Fe)؛ واکنش استری‌شدن؛ بیودیزل | ||
| عنوان مقاله [English] | ||
| Biodiesel production by a novel composite of Fe (III)-based MOF and phosphomolybdic acid as an efficient and heterogeneous catalyst | ||
| نویسندگان [English] | ||
| Soraya Parak1؛ Ahmad Nikseresht2؛ mohammad alikarami1 | ||
| 1Department of Chemistry, Ilam Branch, Islamic Azad University, Ilam, Iran | ||
| 2Department of Chemistry, Payame Noor University (PNU), P.OBox: 19395-4697 Tehran, Iran | ||
| چکیده [English] | ||
| The synthesis of MIL-53(Fe) samples and encapsulation process of phosphomolybdic acid implemented using ultrasound at ambient temperature and atmospheric pressure. Characterization of newly synthesized nanocomposite was carried out using various techniques such as XRD, FT-IR, SEM, EDS, BET and ICP. The catalytic activity of the prepared nanocomposites, PMA@MIL-53(Fe), was tested through the esterification reaction of oleic acid with ethanol under ultrasonic irradiation. Biodiesel production process using certain molar ratio of oleic acid/ethanol, PMA@MIL-53(Fe) as catalyst (10-200 mg) containing different amounts of PMA (0-40%), at different reaction times (5-20 minutes), total energy consumption (in watts, W) and ambient temperature under ultrasound conditions. The operating conditions of each of parameters were varied to study their effects on product yield. The results indicated that the synthesized composites show excellent catalytic activity. by encapsulating heteropoly acids in the MOF network, the challenges of using heteropoly acids, such as low contact surface and high solubility, are largely eliminated. The use of heteropoly acids in the industrial scales shows promise, provided the mentioned problems can be overcome | ||
| کلیدواژه‌ها [English] | ||
| Phosphomolybdic acid, Biodiesel, Metal-organic framework, PMA@MIL-53(Fe), Heteropoly acid, heterogeneous catalyst | ||
| مراجع | ||
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